Research Line 1


Optimized and scalable COreduction by tuning reaction environment and transport properties

Prof.dr. G. Mul, University of Twente

Projectnumber P17-08 project 1

This project focuses on fundamental understanding and practical optimization of electro-conversion processes in gas diffusion cells. It takes cathodic CO2 reduction to ethylene or Syngas (mixture of CO and H2), and the concomitant, anodic oxidation of sulphide as reactions to demonstrate the functionality of computational models we derive to describe the relevant transport phenomena. At the same time, a lab-demonstrator will be constructed to demonstrate the practical feasibility of electrochemical conversion of industrial waste gasses containing these components. The computational models of the transport phenomena at all relevant length scales will also serve as input for the device designs of projects 2-5.

Main deliverables and timing

D1.1. Procedure to create gas diffusion structures (GDS) with well-defined pore size and pitch (M25)

D1.2. Procedure to create catalyst layers with well-defined thickness and nanoparticle composition (M36)

D1.3. 1D model to optimize the design of the flow channel and the membrane-electrode assembly (M36)

D1.4. 3D computational model including electro-kinetics (M30)

D1.5. 3D computational model including bubble formation and transport (M42)

D1.6. Working demonstrator cell combining cathodic and anodic gas treatment, exemplary for intensification of processing of industrial waste and/or blast-furnace gas. (M48)


People

Prof.dr. G. Mul

University of Twente

Research Line Leader

Prof.dr.ir. J.T. Padding

Delft University of Technology

Dr. T.E. Burdyny

Delft University of Technology

Prof. W. Smith

Delft University of Technology

Dr.ir. J.W. Haverkort

Delft University of Technology

J.W.B. Blake

Ph.D. Candidate